Descriptive Inorganic Chemistry Second Edition
Buku ini diterbitkan Tahun 2010 Oleh Elsevier Inc. All rights reserved. California. Adalah buku edisi Kedua.
Judul: Descriptive Inorganic Chemistry Second Edition
Oleh: James E. House, et al
Penerbit: Elsevier Inc. All rights reserved. California.
Tahun: 2010
Jumlah Halaman: 585 hal.
Penulis:
James E. House
Kathleen A. House
Illinois Wesleyan University
Bloomington, Illinois
Lingkup Pembahasan:
Buku ini meliputi pembahasan tentang: Dari mana semua itu Datang, Atom dan Struktur Molekul,
Ionic Bonding, Kristal, dan Antarmolekul Angkatan; Reaksi dan Hubungan Energi; Asam, Basa, dan Pelarut tak berair; Hidrogen; Grup IA dan IIA Logam; Boron; Aluminium, Gallium, Indium, dan Thallium; Carbon; Silicon, Germanium, Tin, dan Lead; Nitrogen; Fosfor, arsenik, antimon, dan Bismuth; Oxygen; Sulfur, Selenium, dan Telurium; Halogen; The Noble Gas; Transisi Logam; Struktur dan Bonding di Koordinasi Senyawa; Sintesis dan Reaksi Koordinasi Senyawa; dan Organologam Senyawa.
Daftar Isi:
Preface xv
Chapter 1: Where It All Comes From 1
1.1 The Structure of the Earth 1
1.2 Composition of the Earth’s Crust 4
1.3 Rocks and Minerals 4
1.4 Weathering 5
1.5 Obtaining Metals 6
1.6 Some Metals Today 10
1.7 Nonmetallic Inorganic Minerals 12
References for Further Reading 15
Problems 15
Chapter 2: Atomic and Molecular Structure 17
2.1 Atomic Structure 17
2.2 Properties of Atoms 23
2.3 Molecular Structure 31
2.4 Symmetry 44
2.5 Resonance 51
References for Further Reading 57
Problems 57
Chapter 3: Ionic Bonding, Crystals, and Intermolecular Forces 63
3.1 Ionic Bonds 63
3.2 Intermolecular Interactions 76
References for Further Reading 88
Problems 88
Chapter 4: Reactions and Energy Relationships 91
4.1 Thermodynamic Considerations 91
4.2 Combination Reactions 103
4.3 Decomposition Reactions 105
4.4 Redox Reactions 107
4.5 Hydrolysis Reactions 108
4.6 Replacement Reactions 109
4.7 Metathesis 110
4.8 Neutralization Reactions 112
References for Further Reading 114
Problems 114
Chapter 5: Acids, Bases, and Nonaqueous Solvents 119
5.1 Acid-Base Chemistry 119
5.2 Nonaqueous Solvents 136
5.3 Superacids 148
References for Further Reading 149
Problems 149
Chapter 6: Hydrogen 153
6.1 Elemental and Positive Hydrogen 153
6.2 Occurrence and Properties 158
6.3 Hydrides 160
References for Further Reading 166
Problems 167
Chapter 7: The Group IA and IIA Metals 169
7.1 General Characteristics 170
7.2 Oxides and Hydroxides 175
7.3 Halides 178
7.4 Sulfides 179
7.5 Nitrides and Phosphides 180
7.6 Carbides, Cyanides, Cyanamides, and Amides 181
7.7 Carbonates, Nitrates, Sulfates, and Phosphates 182
7.8 Organic Derivatives 183
References for Further Reading 186
Problems 187
Chapter 8: Boron 189
8.1 Elemental Boron 189
8.2 Bonding in Boron Compounds 191
8.3 Boron Compounds 191
References for Further Reading 203
Problems 204
Chapter 9: Aluminum, Gallium, Indium, and Thallium 207
9.1 The Elements 207
9.2 Oxides 211
9.3 Hydrides 214
9.4 Halides 215
9.5 Other Compounds 217
9.6 Organometallic Compounds 219
References for Further Reading 222
Problems 222
Chapter 10: Carbon 225
10.1 The Element 225
10.2 Industrial Uses of Carbon 229
10.3 Carbon Compounds 231
10.4 Fullerenes 242
References for Further Reading 243
Problems 244
Chapter 11: Silicon, Germanium, Tin, and Lead 247
11.1 The Elements 247
11.2 Hydrides of the Group IVA Elements 251
11.3 Oxides of the Group IVA Elements 252
11.4 Silicates 258
11.5 Zeolites 263
11.6 Halides of the Group IVA Elements 265
11.7 Organic Compounds 269
11.8 Miscellaneous Compounds 271
References for Further Reading 273
Problems 274
Chapter 12: Nitrogen 277
12.1 Elemental Nitrogen 277
12.2 Nitrides 278
12.3 Ammonia and Aquo Compounds 279
12.4 Hydrogen Compounds 280
12.5 Nitrogen Halides 286
12.6 Nitrogen Oxides 288
12.7 Oxyacids 293
References for Further Reading 297
Problems 297
Chapter 13: Phosphorus, Arsenic, Antimony, and Bismuth 301
13.1 Occurrence 301
13.2 Preparation and Properties of the Elements 302
13.3 Hydrides 303
13.4 Oxides 305
13.5 Sulfides 307
13.6 Halides 308
13.7 Phosphonitrilic Compounds 315
13.8 Acids and Their Salts 317
13.9 Fertilizer Production 323
References for Further Reading 325
Problems 326
Chapter 14: Oxygen 329
14.1 Elemental Oxygen, O2 329
14.2 Ozone, O3 331
14.3 Preparation of Oxygen 333
14.4 Binary Compounds of Oxygen 333
14.5 Positive Oxygen 338
References for Further Reading 339
Problems 339
Chapter 15: Sulfur, Selenium, and Tellurium 341
15.1 Occurrence of Sulfur 341
15.2 Occurrence of Selenium and Tellurium 343
15.3 Elemental Sulfur 344
15.4 Elemental Selenium and Tellurium 346
15.5 Reactions of Elemental Selenium and Tellurium 347
15.6 Hydrogen Compounds 348
15.7 Oxides of Sulfur, Selenium, and Tellurium 350
15.8 Halogen Compounds 353
15.9 Nitrogen Compounds 356
15.10 Oxyhalides of Sulfur and Selenium 359
15.11 Oxyacids of Sulfur, Selenium, and Tellurium 362
15.12 Sulfuric Acid 367
References for Further Reading 372
Problems 372
Chapter 16: Halogens 375
16.1 Occurrence 375
16.2 The Elements 376
16.3 Interhalogens 378
16.4 Polyatomic Cations and Anions 384
16.5 Hydrogen Halides 387
16.6 Oxides 389
16.7 Oxyacids and Oxyanions 394
References for Further Reading 398
Problems 398
Chapter 17: The Noble Gases 401
17.1 The Elements 401
17.2 The Xenon Fluorides 404
17.3 Reactions of Xenon Fluorides 407
17.4 Oxyfluorides and Oxides 409
References for Further Reading 410
Problems 411
Chapter 18: The Transition Metals 413
18.1 The Metals 413
18.2 Oxides 424
18.3 Halides and Oxyhalides 430
18.4 Miscellaneous Compounds 432
18.5 The Lanthanides 434
References for Further Reading 437
Problems 437
Chapter 19: Structure and Bonding in Coordination Compounds 441
19.1 Types of Ligands and Complexes 441
19.2 Naming Coordination Compounds 444
19.3 Isomerism 446
19.4 Factors Affecting the Stability of Complexes 451
19.5 A Valence Bond Approach to Bonding in Complexes 455
19.6 Back Donation 461
19.7 Ligand Field Theory 464
19.8 Jahn-Teller Distortion 473
References for Further Reading 474
Problems 475
Chapter 20: Synthesis and Reactions of Coordination Compounds 479
20.1 Synthesis of Coordination Compounds 479
20.2 A Survey of Reaction Types 484
20.3 A Closer Look at Substitution Reactions 493
20.4 Substitution in Square Planar Complexes 496
20.5 Substitution in Octahedral Complexes 505
References for Further Reading 511
Problems 512
Chapter 21: Organometallic Compounds 517
21.1 Structure and Bonding in Metal Alkyls 518
21.2 Preparation of Organometallic Compounds 522
21.3 Reactions of Metal Alkyls 525
21.4 Cyclopentadienyl Complexes (Metallocenes) 528
21.5 Metal Carbonyl Complexes 531
21.6 Metal Olefin Complexes 541
21.7 Complexes of Benzene and Related Aromatics 545
References for Further Reading 546
Problems 547
Appendix A: Ground State Electron Configurations of Atoms 551
Appendix B: Ionization Energies 555
Index 559
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